CHEMICAL LEACHING OF CONTAMINATED SOIL – CASE STUDY
This study presents results of chemical leaching of contaminated soil from several metallurgically loaded locality of Richnava in Slovakia, applying two chelants – Na2EDTA and Na3EDDS of different molar concentration, done at different leaching conditions. The lower molar concentration (2 mM) of chelants showed comparable effect on Mn, Ni, As...
By Zuzana Danková, Iveta Štyriaková, Ľubica Kovaničová, Katarína Čechovská, Marián Košuth, Jaroslav Šuba, Jarmila Nováková, Patrik Konečný, Ľubomír Tuček, Katarína Žecová, Eva Lenhardtová, Zoltán Németh
COLUMN SORPTION OF TOXIC IONS IN VARIOUS QUARTZ SAND - PACKED COLUMNS
In this study the adsorption of As(V), Cu(II) and Zn(II) ions from multi-species model solution was tested in dynamic conditions in sand columns containing a thin layer of bentonite (B), iron-based sludge (IS) and synthetic magnetic particles (MP). Adsorption experiments were performed in order to evaluate the removal efficiency and selectivity of ...
By Alexandra Bekényiová, Zuzana Danková, Michal Hegedüs, Zuzana Mitróová, Silvia Dolinská, Ingrid Znamenáčková
ELIMINATION OF TOXIC ELEMENTS BY NATURAL AND SYNTHETIC ADSORBENTS
The adsorption of Zn(II) and Cu(II) onto siderite (S) and kaolin (K) and adsorption of As(V) onto bentonite (B) was studied. The chemical modification – precipitation of MnO2 on the kaolin (KM) and siderite (SM) surface was used to improve the adsorption properties of natural materials for their application in columns. In the batch tests the higher...
By Zuzana Danková, Alexandra Bekényiová, Zuzana Mitróová, Danka Gešperová
STUDY OF Cu(II) ADSORPTION BY BENTONITE AND FOLLOWING REGENERATION BY BIOLEACHING
The natural bentonite and bentonite/iron oxide composite were used as sorbents of Cu(II). Their sorption properties were examined under the different conditions such as pH of the solution, initial metal ion concentration. The bentonite removed 71 % Cu(II) while composite 90 %. Their maximum adsorption capacities were 34.1 and 44.4 mg Cu(II) g -1, r...
By Zuzana Danková, Zuzana Dakos, Iveta Štyriaková, Alexandra Bekényiová
BENTONITE/IRON OXIDE MAGNETIC COMPOSITES: CHARACTERIZATION AND APPLICATION AS Pb(II) ADSORBENTS
The natural clay bentonite (B) as adsorbent of lead cations was studied. To enhance its adsorption capacity, the coating by iron oxide particles, in two selected weight ratios: 2:1 (BM1) and 4:1(BM2), was used. The changes of the textural and surface parameters after the modification were studied by the low temperature nitrogen adsorption, XRD and ...
By Zuzana Danková, Erika Fedorová, Alexandra Bekényiová
SORPTION OF COPPER AND ZINC BY GOETHITE AND HEMATITE
In the present work, the abilities of natural and synthetic samples of goethite and hematite to remove copper Cu(II) ) and zinc Zn(II) ions from aqueous solutions were compared. Batch adsorption experiments were performed in order to evaluate the removal efficiency of iron oxide samples. The effect of initial metal ion concentration, initial pH and...
By Alexandra Bekényiová, Iveta Štyriaková, Zuzana Danková
SURFACE AND STRUCTURE STUDY OF CLAY-BASED COMPOSITES AFTER THERMAL TREATMENT
The composite materials prepared from clay and iron oxides in different weight ratios and temperatures denoted as A85 and E20 were heated at 300 °C in reductive atmosphere and up to 650 °C in inert atmosphere. The changes in the structure, surface and pore properties were examined by XRD, N2 adsorption method and TG, DTA method. The morphology was ...
By Annamária Mockovčiaková, Zuzana Danková, Jaroslav Briančin