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Original scientific article
Published: December 2012 Chemical Tehnology
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https://doi.org/10.5825/afts.2012.0407.049O

EFFECT OF THERMAL TREATMENT ON THE BENTONITE PROPERTIES

By
Zuzana Orolínová ,
Zuzana Orolínová

Institute of Geotechnics, Slovak Academy of Sciences Košice , Košice , Slovakia

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Annamária Mockovčiaková ,
Annamária Mockovčiaková

Institute of Geotechnics, Slovak Academy of Sciences Košice , Košice , Slovakia

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Silvia Dolinská ,
Silvia Dolinská

Institute of Geotechnics, Slovak Academy of Sciences Košice , Košice , Slovakia

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Jaroslav Briančin
Jaroslav Briančin

Institute of Geotechnics, Slovak Academy of Sciences Košice , Košice , Slovakia

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Abstract

The main objective of this study is to investigate the changes in structure, surface area and porosity of monomineral fraction of the local bentonite upon heating at 300, 500 and 650 °C. IR spectroscopy, DTA, XRD and N2 adsorption method were employed for the analyses. The non-heated montmorillonite was characterized by a basal spacing of 1.50 nm, after thermal treatment of 0.98 nm. This decrease was attributed to the loss of interlamellar water, finally a phase transformation occured. Changes of the crystal structure related with the decrease of the value of specific surface area and total pore volume.

Keywords:

bentonite,
thermal treatment,
surface properties.

References

1.
Dellisanti F, Minguzzi V, Valdrè G. Thermal and structural properties of Ca-rich Montmorillonite mechanically deformed by compaction and shear. 2006;31(3–4):282–9.
2.
Önal M, Sarıkaya Y. Thermal behavior of a bentonite. 2007;90(1):167–72.
3.
Eren E, Afsin B. An investigation of Cu(II) adsorption by raw and acid-activated bentonite: A combined potentiometric, thermodynamic, XRD, IR, DTA study. 2008;151(2–3):682–91.
4.
Konta J. Textural Variation and Composition of Bentonite Derived from Basaltic Ash. 1986;34(3):257–65.
5.
Murad E. The characterization of soils, clays and clay firing products. Hyperfine Interactions. 1998;111.
6.
Murad E, Johnston JH. Iron oxides and oxyhydroxides. Mössbauer spectroscopy applied to inorganic chemistry. Vol. 2. 1987.
7.
Storck S, Bretinger H, Maier WF. Characterization of micro- and mesoporous solids by physisorption methods and pore-size analysis. 1998;174(1–2):137–46.
8.
Hudec P, Novanský J, Šilhár S, Trung T, Zúbek M, Maďar J. Possibility of using t-plots, obtained from nitrogen adsorption for the valuation of zeolites. Adsorption Science and Technology. 1986;3:159–66.
9.
Sing KSW. Reporting physisorption data for gas/solid systems with special reference to the determination of surface area and porosity (Recommendations 1984). 1985;57(4):603–19.
10.
Lagarec K, Rancourt DG. Recoil-Mössbauer spectral analysis software for Windows, Version.02. 1998.
11.
Jesenák K, Kuchta Ľ, Guller L, Fúsková J. Physico-chemical Properties of Bentonite “Stará Kremnička - Jelšový potok”: I. Particle Size Distribution Mineralia Slovaca. 1997;29:439–42.
12.
Bhattacharyya KG, Gupta SS. Adsorption of a few heavy metals on natural and modified kaolinite and montmorillonite: A review. 2008;140(2):114–31.
13.
Karmous MS, Rhaiem HB, Naamen S, Oueslati W, Amara ABH. The interlayer structure and thermal behavior of Cu and Ni montmorillonites. 2006;2006(suppl_23_2006):431–6.
14.
A. Karakassides M, Madejová J, Arvaiová B, Bourlinos A, Petridis D, Komadel P. Location of Li(I), Cu(II) and Cd(II) in heated montmorillonite: evidence from specular reflectance infrared and electron spin resonance spectroscopies. 1999;9(7):1553.
15.
Seiffarth T, Kaps C. Structural Characterization of (Cu&lt;SUP&gt;2+&lt;/SUP&gt;,Na&lt;SUP&gt;+&lt;/SUP&gt;)- and (Cu&lt;SUP&gt;2+&lt;/SUP&gt;,NH&lt;SUB&gt;4&lt;/SUB&gt;&lt;SUP&gt;+&lt;/SUP&gt;)-Exchanged Bentonites upon Thermal Treatment. 2009;57(1):40–5.
16.
Sarikaya Y. The Effect of Thermal Treatment on Some of the Physicochemical Properties of a Bentonite. 2000;48(5):557–62.
17.
Mirza J, Riaz M, Naseer A, Rehman F, Khan AN, Ali Q. Pakistani bentonite in mortars and concrete as low cost construction material. 2009;45(4):220–6.
18.
Valanciene V, Siauciunas R, Baltusnikaite J. The influence of mineralogical composition on the colour of clay body. 2010;30(7):1609–17.
19.
García R. A, Domínguez-Ríos C, Bocanegra-Bernal MH, Aguilar-Elguézabal A. Use of thermally treated bentonitic clay in the formulation of ceramic tiles. 2009;46(3):271–6.
20.
Lee JY, Lee HK. Characterization of organobentonite used for polymer nanocomposites. 2004;85(2–3):410–5.
21.
Kooli F, Bovey J, Jones W. Dependence of the properties of titanium-pillared clays on the host matrix: a comparison of montmorillonite, saponite and rectorite pillared materials. 1997;7(1):153–8.
22.
Pinnavaia TJ. Intercalated Clay Catalysts. 1983;220(4595):365–71.

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This is an open access article distributed under the  Creative Commons Attribution Non-Commercial License (CC BY-NC) License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 

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Issue 7, 2012
NEKI ASPEKTI SEIZMIČKOG RIZIKA GRAĐEVINSKOG PROSTORA TERMOELEKTRANE UGLJEVIK – 3 RADON U VODAMA SEIZMIČKI AKTIVNIH ZONA TUZLANSKE REGIJE ANALIZA KONCENTRACIJE RADONA U SEIZMIČKI AKTIVNIM ZONAMA TUZLANSKE REGIJE RAZVIJANJE KORELACIJA IZMEĐU MEHANIČKIH OSOBINA TLA DEFINISANJE MAKSIMALNOG KORAKA NAPREDOVANJA MEHANIZOVANE HIDRAULIČNE PODGRADE (MHP) ZA USLOVE RUDNIKA „STRMOSTEN“ See full issue

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